From Here to Eternity (1953) With Montgomery Clift, Frank Sinatra, and Burt Lancaster. In case you're wondering about that Superman reference, that's not in the original movie. Whoever originally posted this on YouTube is pointing out that George Reeves, who played the Man of Steel in the 1950s, is in the background.
Marty (1955) It was for this role that Grace Kelly handed Borgnine an Academy Award.
And now, from the sublime to the ridiculous:
Spongebob SquarePants. Borgnine is Mermaid Man, and his old McHale's Navy sidekick Tim Conway is Barnacle Boy.